The tetrahedral geometry of four-coordinate carbon atoms is a steadfast property of organic compounds. Nevertheless, chemists are still attracted to the possibility of twisting or squashing a ...
Researchers from The University of Osaka report a new class of transition metal complexes with direct nickel-boron bonds without additional support Osaka, Japan – The arrangement of small molecules – ...
Do unusual geometries always come from the force exerted by a protein, a solid-state lattice or bulky ligands? In a new iron(II) complex, simple ligands stabilize a square-planar high-spin complex ...
The field of spin transition has been dominated by six-coordinate octahedral metal ions, but now an unusual spin transition has been found for an oxide containing a square-planar coordinate iron(II).
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