20.14 α,β-Unsaturated Carbonyl Compounds
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20.14 α,β-Unsaturated Carbonyl Compounds
20.14 α,β-Unsaturated Carbonyl Compounds
Apr 2, 2015
Carbonyl Group Reactions
The Fischer–Speier esterification enables the acid-catalyzed formation of esters from carboxylic acids and alcohols under equilibrium conditions. Developed by Emil Fischer and Arthur Speier in the late 19th century, the reaction proceeds via protonation of the carbonyl group, nucleophilic attack by the alcohol, and subsequent elimination of water to form the ester. Learn. Review. Repeat.
0:13
The Fischer–Speier esterification enables the acid-catalyzed formation of esters from carboxylic acids and alcohols under equilibrium conditions. Developed by Emil Fischer and Arthur Speier in the late 19th century, the reaction proceeds via protonation of the carbonyl group, nucleophilic attack by the alcohol, and subsequent elimination of water to form the ester. Learn. Review. Repeat.
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The Baeyer–Villiger oxidation enables the conversion of ketones into esters and cyclic ketones into lactones via oxygen insertion adjacent to the carbonyl group. Developed by Adolf von Baeyer and Victor Villiger in the late 19th century, the reaction proceeds through formation of a Criegee intermediate followed by migratory rearrangement, with group migration governed by migratory aptitude. Learn. Review. Repeat.
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The Baeyer–Villiger oxidation enables the conversion of ketones into esters and cyclic ketones into lactones via oxygen insertion adjacent to the carbonyl group. Developed by Adolf von Baeyer and Victor Villiger in the late 19th century, the reaction proceeds through formation of a Criegee intermediate followed by migratory rearrangement, with group migration governed by migratory aptitude. Learn. Review. Repeat.
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Why Carboxylic Acid Does Not Give Reactions of Carbonyl Group? - Chemistry | Shaalaa.com
Why Carboxylic Acid Does Not Give Reactions of Carbonyl Group? - Chemistry | Shaalaa.com
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